This list is a personal opinion. Therefore, any songs that were big and are low, doesn't mean they aren't famous, it means I don't enjoy them as much. PYN Below if you want to be tagged.
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Title: Honky Tonk Women
Album: Through the Past, Darkly (Big Hits Vol. 2)
Year: 1968
Uh so, this is going to be a bit confusing for a song in this list. This was never ACTUALLY released on an album, yet it was put on an album containing hits from their first few years. A country version of the song was ranked #20, and was on the album let it bleed.
MORE COWBELL! As the SNL skit goes, we do seriously need more cowbell in songs. Go check out Mountain's "Mississippi Queen", it is also a great song. This song has just the right amount of each subtle instrument, and a great voice change from Jagger. This is the Rolling Stones entering their fucking prime.